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Home > Product > Organic Building Blocks > Organic Silicon Compounds > Alkyl Silane > (Chloromethyl)dimethylphenylsilane

(Chloromethyl)dimethylphenylsilane | CAS Number: 1833-51-8

Catalog Number
ACM1833518
Product Name
(Chloromethyl)dimethylphenylsilane
Structure
CAS Number
1833-51-8
IUPAC Name
chloromethyl-dimethyl-phenylsilane
Synonyms
chloromethyl-phenyldimethylsilane; dimethylphenylchloromethylsilane; (dimethylphenylsilyl)-methyl chloride; (Chloromethyl)dimethyl(phenyl)silane; PhMe2SiCH2Cl; Dichloromethyldimethylphenylsilane; Phenyldimethyl(chloromethyl)silane; Me2PhSiCH2Cl; ChloroMethyldiMethylphenylsilane; (Chloromethyl)dimethylphenylsilane; Silane,(chloromethyl)dimethylphenyl;
Category
Halogen hydroxyl silane
Molecular Weight
184.74
Exact Mass
184.04800
Molecular Formula
C9H13ClSi
Boiling Point
223.8ºC at 760mmHg
Flash Point
91.1ºC
Density
0.99g/cm3
Purity
95%+
Appearance
Transparent liquid
Safty Description
26-36
Hazard Statements
Xi: Irritant;
WGK Germany
3
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1Direct chemical synthesis of chiral methanol of 98% ee and its conversion to [(2)H1,(3)H]methyl tosylate and [(2)H1,(3)H-methyl]methionine.

Peric Simov B1, Wuggenig F, Mereiter K, Andres H, France J, Schnelli P, Hammerschmidt F.

J Am Chem Soc. 2005 Oct 12;127(40):13934-40.

This paper describes the synthesis of chiral methanols [(R)- and (S)-CHDTOH] in a total of 12 steps starting from (chloromethyl)dimethylphenylsilane. The metalated carbamates derived from (dimethylphenylsilyl)methanol and secondary amines were borylated at low temperatures (-78 or -94 degrees C) using borates derived from tert-butyl alcohol and (+)-pinane-2,3-diol or (R,R)-1,2-dicyclohexylethane-1,2-diol to give diastereomeric boronates (dr 1:1 to 5:1). Read More

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Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA