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(2-Bromoethyl)trimethylsilane | CAS Number: 18156-67-7

Catalog Number
ACM18156677
Product Name
(2-Bromoethyl)trimethylsilane
Structure
CAS Number
18156-67-7
IUPAC Name
2-bromoethyl(trimethyl)silane
Synonyms
(2-Bromoethyl)trimethylsilane, 18156-67-7, ACMC-1BR2G, AGN-PC-00DPNR, 2-(Trimethylsilyl)ethyl Bromide, CTK4D7917, Silane,(2-bromoethyl)trimethyl-, Silane, (2-bromoethyl)trimethyl-, AKOS006228000, AG-E-31543, B2216, I14-94458
Category
Halogen hydroxyl silane
Molecular Weight
181.15
Exact Mass
179.99700
Molecular Formula
C5H13BrSi
Boiling Point
149.555ºC at 760 mmHg
Flash Point
46.759ºC
Density
1.15
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)CCBr
InChIKey
HYRIFSNOTHOUQJ-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Safty Description
S26
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1The first Cu(I)-mediated nucleophilic trifluoromethylation reactions using (trifluoromethyl)trimethylsilane in ionic liquids.

Kim J1, Shreeve JM.

Org Biomol Chem. 2004 Oct 7;2(19):2728-34. Epub 2004 Sep 3.

The new ionic liquids (5a-8a) were used as reaction media for nucleophilic trifluoromethylation reactions of trifluoromethyl(trimethyl)silane with (1) aryl, allyl, benzyl, and alkyl halides in Cu(I)-mediated C-C bond formation reactions, and (2) carbonyl functionalities catalyzed with Ph3P or CsF. In addition, conversion of benzyl bromide as a model compound to benzyl fluoride was examined in using 6a CsF as the fluorinating reagent. Read More

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Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA