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1,2-Bis(dimethylsilyl)benzene | CAS Number: 17985-72-7

Catalog Number
ACM17985727
Product Name
1,2-Bis(dimethylsilyl)benzene
Structure
CAS Number
17985-72-7
IUPAC Name
[2-(dimethyl-$l^{3}-silanyl)phenyl]-dimethylsilicon
Synonyms
1,2-Bis(dimethylsilyl)benzene, 17985-72-7, o-Phenylenebis(dimethylsilane), [2-(dimethyl-, AC1MBZSF, ACMC-209efy, AC1O4CNB, SureCN148575, 14804_ALDRICH, 14804_FLUKA, CTK3J0706, QAUCEYVYCBYVDK-UHFFFAOYSA-, 1,2-Phenylenebis(dimethylsilane), MolPort-003-926-555, ANW-22988, (2-dimethylsilylphenyl)-dimethylsilane, AKOS015840027, AKOS015888396, AG-E-30099, AK126571
Category
Symmetric bis-silane
Molecular Weight
194.42
Exact Mass
194.09500
Molecular Formula
C10H18Si2
Boiling Point
129ºC (50 mmHg)
Flash Point
71ºC
Density
0.89
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)C1=CC=CC=C1[Si](C)C
InChIKey
MUUXBTFQEXVEEI-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Safty Description
S24/25
WGK Germany
3
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1Theoretical Study of the Catalytic Hydrogenation of Alkenes by a Disilaferracyclic Complex: Can the Fe-Si σ-Bond-Assisted Activation of H-H Bonds Allow Development of a Catalysis of Iron?

Tahara A, Tanaka H, Sunada Y, Shiota Y, Yoshizawa K, Nagashima H1.

J Org Chem. 2016 Nov 18;81(22):10900-10911. Epub 2016 Oct 17.

The mechanisms associated with the hydrogenation of alkenes catalyzed by the iron complex Fe(cis-CO)2{o-(SiMe2)2C6H4}2(H)2 (1) were investigated by DFT calculations. The complex 1 has a structure in which the iron center is bonded to four silicon atoms and two hydrides. Secondary Si···H···Si interactions were also observed. The exchange of a 1,2-bis(dimethylsilyl)benzene ligand with ethylene and hydrogen gives a disilaferracycle bearing η2-(CH2═CH2) and η2-H2 ligands. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA