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Benzyldimethylchlorosilane | CAS Number: 1631-70-5

Catalog Number
ACM1631705
Product Name
Benzyldimethylchlorosilane
Structure
CAS Number
1631-70-5
IUPAC Name
benzyl(dimethyl)silicon
Synonyms
benzyldimethylsilyl; Benzyldimethylsilane;
Category
Organic hydrogen silane
Molecular Weight
150.29
Exact Mass
150.08600
Molecular Formula
C9H14Si
Boiling Point
69-71ºC (15 mmHg)
Flash Point
56ºC
Density
0.949
Purity
95%+
Appearance
Transparent liquid
Safty Description
S26-S36
Hazard Statements
Xi:Irritant;
WGK Germany
3
Packing Group
III
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1Iridium-catalyzed (Z)-trialkylsilylation of terminal olefins.

Lu B1, Falck JR.

J Org Chem. 2010 Mar 5;75(5):1701-5. doi: 10.1021/jo902678p.

A complex of commercial [Ir(OMe)(cod)](2) and 4,4-di-tert-butyl-2,2-bipyridine (dtbpy) catalyzes the Z-selective, dehydrative silylation of terminal alkenes, but not 1,2-disubstituted alkenes, with triethylsilane or benzyldimethylsilane in THF at 40 degrees C. Yields and Z-stereoselectivity were significantly improved by 2-norbornene, in contrast with other sacrificial alkenes. The reaction is compatible with many functional groups including epoxides, ketones, amides, alcohols, esters, halides, ketals, and silanes. Read More

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA