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Home > Product > Organic Building Blocks > Organic Silicon Compounds > Other Organosilicon > Pyridine,2-methyl-6-[(trimethylsilyl)methyl]-

Pyridine,2-methyl-6-[(trimethylsilyl)methyl]- | CAS Number: 158588-04-6

Catalog Number
ACM158588046
Product Name
Pyridine,2-methyl-6-[(trimethylsilyl)methyl]-
Structure
CAS Number
158588-04-6
IUPAC Name
ethyl 7-benzyl-4-oxo-1,5,6,8-tetrahydro-1,7-naphthyridine-3-carboxylate
Synonyms
ethyl 7-benzyl-4-hydroxy-5,6,7,8-tetrahydro-1,7-naphthyridine-3-carboxylate, 1207176-20-2, PubChem23216, CTK6F7185, AKOS015839377, AG-B-21882, AK-49208, KB-51476, 102200-79-3, 158588-04-6
Category
Ammonia hydroxyl silane
Molecular Weight
312.363000 [g/mol]
Molecular Formula
C10H17NSi
Purity
95%+
Appearance
Transparent liquid
InChIKey
PPRZIPDYUCSLLE-UHFFFAOYSA-N
H-Bond Donor
1
H-Bond Acceptor
5
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1Rhodium-catalyzed silylation of aromatic carbon-hydrogen bonds in 2-arylpyridines with disilane.

Tobisu M1, Ano Y, Chatani N.

Chem Asian J. 2008 Sep 1;3(8-9):1585-91. doi: 10.1002/asia.200800090.

The rhodium(I)-catalyzed regioselective silylation of the ortho carbon-hydrogen bond in 2-arylpyridines with disilane is described. For example, the reaction of 2-(2-methylphenyl)pyridine with 2 equivalents of hexamethyldisilane in the presence of 5 mol % [RhCl(cod)](2) (cod=1,5-cyclooctadiene) in o-xylene at 130 degrees C for 15 h gave 2-[2-methyl-6-(trimethylsilyl)phenyl]pyridine in 86 % yield. In contrast to silylation with hydrosilanes, hydrogen acceptors are not required to achieve high conversion. Read More

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Tel:1-201-478-8534
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