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Home > Product > Organic Silicon Compounds > Silanols > 2-(Trimethylsilyl)phenol

2-(Trimethylsilyl)phenol | CAS Number: 15288-53-6

Catalog Number
ACM15288536
Product Name
2-(Trimethylsilyl)phenol
Structure
CAS Number
15288-53-6
Category
Hydroxyl alkyl silane
Purity
95%+
Appearance
Colorless solid
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1Palladium-Catalyzed Desilylative Acyloxylation of Silicon-Carbon Bonds on (Trimethylsilyl)arenes: Synthesis of Phenol Derivatives from Trimethylsilylarenes.

Gondo K1, Oyamada J1, Kitamura T1.

Org Lett. 2015 Oct 2;17(19):4778-81. doi: 10.1021/acs.orglett.5b02336.

A strategy for desilylative acetoxylation of (trimethylsilyl)arenes has been developed in which (trimethylsilyl)arenes are converted into acetoxyarenes. The direct acetoxylation is performed in the presence of 5 mol % of Pd(OAc)2 and PhI(OCOCF3)2 (1.5 equiv) in AcOH at 80 °C for 17 h. The acetoxyarenes are obtained in good to high yields (67-98%). The synthetic utility is demonstrated with a one-pot transformation of (trimethylsilyl)arenes to phenols by successive acetoxylation and hydrolysis. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA