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Home > Product > Organic Silicon Compounds > Siloxanes > Acryloxytrimethylsilane

Acryloxytrimethylsilane | CAS Number: 13688-55-6

Catalog Number
ACM13688556
Product Name
Acryloxytrimethylsilane
Structure
CAS Number
13688-55-6
IUPAC Name
trimethylsilyl prop-2-enoate
Synonyms
Trimethylsilyl acrylate, Acrylic acid trimethylsilanyl ester, 13688-55-6, Acrylic acid, trimethylsilyl ester, AC1LBB27, ACMC-1BO71, trimethylsilyl prop-2-enoate, ACRYLOXYTRIMETHYLSILANE, 560138_ALDRICH, AC1Q5X87, CTK4C0531, AR-1L7496, 2-Propenoic acid,trimethylsilyl ester, AKOS015909472, 2-Propenoic acid, trimethylsilyl ester, AG-K-70952, I14-33611, Acrylicacid, trimethylsilyl ester (7CI,8CI);Silanol, trimethyl-, acrylate (6CI);SIA0320;SIA 0320.0;Trimethylsilyl 2-propenoate;Trimethylsilyl acrylate;
Category
Organicacyloxysilane
Molecular Weight
144.24
Exact Mass
144.06100
Molecular Formula
C6H12O2Si
Boiling Point
53ºC0.2 mm Hg(lit.)
Flash Point
5 °F
Density
0.984 g/mL at 25ºC(lit.)
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)OC(=O)C=C
InChIKey
OTYBJBJYBGWBHB-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
2
Safty Description
26-28-61
Hazard Statements
Xi: Irritant;N: Dangerous for the environment;
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1Electrochemical selenium- and iodonium-initiated cyclisation of hydroxy-functionalised 1,4-dienes.

Röse P1, Emge S1, Yoshida J2, Hilt G1.

Beilstein J Org Chem. 2015 Jan 28;11:174-83. doi: 10.3762/bjoc.11.18. eCollection 2015.

The cobalt(I)-catalysed 1,4-hydrovinylation reaction of allyloxytrimethylsilane and allyl alcohol with substituted 1,3-dienes leads to hydroxy-functionalised 1,4-dienes in excellent regio- and diastereoselective fashion. Those 1,4-dienols can be converted into tetrahydrofuran and pyran derivatives under indirect electrochemical conditions generating selenium or iodonium cations. The reactions proceed in good yields and regioselectivities for the formation of single diastereomers.

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Tel:1-201-478-8534
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