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Home > Product > Organic Silicon Compounds > Other Organosilicon > N-(Trimethylsilyl)morpholine

N-(Trimethylsilyl)morpholine | CAS Number: 13368-42-8

Catalog Number
ACM13368428
Product Name
N-(Trimethylsilyl)morpholine
Structure
CAS Number
13368-42-8
IUPAC Name
trimethyl(morpholin-4-yl)silane
Synonyms
N-(TriMethylsilyl)Morpholine; trimethyl(morpholin-4-yl)silane;
Category
Organic amino silane
Molecular Weight
159.3
Exact Mass
159.10800
Molecular Formula
C7H17NOSi
Boiling Point
160ºC
Flash Point
27ºC
Density
0.897
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)N1CCOCC1
InChIKey
JJOWIQMPCCUIGA-UHFFFAOYSA-N
Safty Description
26-36/37/39-45-16
Hazard Statements
C: Corrosive;
WGK Germany
3
Packing Group
III
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1Palladium-catalyzed one-pot three- or four-component coupling of aryl iodides, alkynes, and amines through C-N bond cleavage: efficient synthesis of indole derivatives.

Hao W1, Geng W, Zhang WX, Xi Z.

Chemistry. 2014 Feb 24;20(9):2605-12. doi: 10.1002/chem.201304215. Epub 2014 Jan 21.

An efficient synthesis of N-substituted indole derivatives was realized by combining the Pd-catalyzed one-pot multicomponent coupling approach with cleavage of the C(sp(3))-N bonds. Three or four components of aryl iodides, alkynes, and amines were involved in this coupling process. The cyclopentadiene-phosphine ligand showed high efficiency. A variety of aryl iodides, including cyclic and acyclic tertiary amino aryl iodides, and substituted 1-bromo-2-iodobenzene derivatives could be used. Read More

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Tel:1-201-478-8534
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