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Home > Product > Insect Pheromone > Ethyl (E)-3-octenoate

Ethyl (E)-3-octenoate | CAS Number: 1117-65-3

Catalog Number
ACM1117653
Product Name
Ethyl (E)-3-octenoate
Structure
CAS Number
1117-65-3
Molecular Weight
270.25
Molecular Formula
C10H18O2
Purity
96%
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1Regio- and stereocontrol in the reactions of α-halo-β,γ-enoates and α-O-phosphono-β,γ-enenitriles with organocuprates.

Dieter RK1, Picado A.

J Org Chem. 2014 Nov 21;79(22):11125-38. doi: 10.1021/jo502111c. Epub 2014 Nov 3.

The reactions of (Z)- and (E)-ethyl 2-chloro-3-octenoate (4a and 17) and (E)- and (Z)-diethyl (1-cyano-2-heptenyl)phosphate (21a and 21b) with organocuprates were investigated as potential substrates for preparing γ-substituted α,β-enoates and enenitriles. In these copper-mediated allylic substitution reactions, the Z-isomer 4a displayed complete regio- and stereoselectivity (i.e., E:Z), while the regio- and stereoselectivity for E-isomer 17 varied as a function of solvent, cuprate reagent, transferable ligand, and cuprate counterion (e. Read More

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Tel:1-201-478-8534
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