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Home > Product > Organic Silicon Compounds > Other Organosilicon > Trimethylsilyl methanesulfonate

Trimethylsilyl methanesulfonate | CAS Number: 10090-05-8

Catalog Number
ACM10090058
Product Name
Trimethylsilyl methanesulfonate
Structure
CAS Number
10090-05-8
EC Number
233-220-2
IUPAC Name
trimethylsilyl methanesulfonate
Synonyms
Trimethylsilylmethanesulfonate, 64296_ALDRICH, Trimethylsilyl methanesulfonate, Trimethylsilyl methanesulphonate, MolPort-003-938-030, CID82345, EINECS 233-220-2, Silanol, trimethyl-, methanesulfonate, I14-3342, 10090-05-8
Category
Organicacyloxysilane
Molecular Weight
168.29
Exact Mass
168.02800
Molecular Formula
C4H12O3SSi
Boiling Point
209.8ºC at 760mmHg
Flash Point
30ºC
Density
1.09
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)OS(=O)(=O)C
InChIKey
BCHASIUOFGDRIO-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
3
Safty Description
23-24/25
WGK Germany
3
Packing Group
II
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1Mechanism of anomerization of cyclohexyl 2-deoxy-3,4,6-tri-O-methyl-2-(N-methylacetamido)-alpha- and beta-D-hexopyranosides under reductive-cleavage conditions.

Ahn YM1, Gray GR.

Carbohydr Res. 1996 Dec 24;296:215-27.

The fully methylated cyclohexyl glycosides of 2-acetamido-2-deoxy-alpha- and beta-D-hexopyranoses having the gluco, manno, and galacto configurations were each subjected to reductive-cleavage conditions using one of three promoters, namely trimethylsilyl trifluoromethanesulfonate, a mixture of trimethylsilyl methanesulfonate and boron trifluoride etherate, or boron trifluoride etherate alone. As expected, the fully methylated 1,2-trans-linked acetamido sugar derivatives were rapidly converted to their respective oxazolinium ions with all three promoters. Read More

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA