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Home > Product > Precious Metal Catalyst > (Acetylacetonato)(norbornadiene)rhodium(I)

(Acetylacetonato)(norbornadiene)rhodium(I) | CAS Number: 32354-50-0

Catalog Number
ACM32354500
Product Name
(Acetylacetonato)(norbornadiene)rhodium(I)
Structure
CAS Number
32354-50-0
MDL Number
MFCD00075071
Synonyms
Norbornadiene(acetylacetonato)rhodium
Molecular Weight
294.15
Molecular Formula
C12H15O2Rh
Melting Point
176-178 °C(lit.)
Appearance
yellow to orange powder
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H315-H319-H335
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1Sulfur-bridged early-late heterobimetallics synthesized by incorporation of titanium, vanadium, and molybdenum into bis(hydrosulfido) templates of group 9 metals.

Kuwata S1, Nagano T, Matsubayashi A, Ishii Y, Hidai M.

Inorg Chem. 2002 Aug 26;41(17):4324-30.

Reactions of the bis(hydrosulfido) complexes [Cp*Rh(SH)(2)(PMe(3))] (1a; Cp* = eta(5)-C(5)Me(5)) with [CpTiCl(3)] (Cp = eta(5)-C(5)H(5)) and [TiCl(4)(thf)(2)] in the presence of triethylamine led to the formation of the sulfido-bridged titanium-rhodium complexes [Cp*Rh(PMe(3))(micro(2)-S)(2)TiClCp] (2a) and [Cp*Rh(PMe(3))(micro2-S)(2)TiCl(2)] (3a), respectively. Complex 3a and its iridium analogue 3b were further converted into the bis(acetylacetonato) complexes [Cp*M(PMe(3))(micro(2)-S)(2)Ti(acac)(2)] (4a, M = Rh; 4b, M = Ir) upon treatment with acetylacetone. Read More

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