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Home > Product > Material & Chemicals > Polymer/Macromolecule > 5-tert-Butylisophthalic acid

5-tert-Butylisophthalic acid | CAS Number: 2359-09-3

Catalog Number
ACM2359093
Product Name
5-tert-Butylisophthalic acid
Structure
CAS Number
2359-09-3
Synonyms
1,3-Benzenedicarboxylicacid,5-(1,1-dimethylethyl)-;3-Benzenedicarboxylicacid,5-(1,1-dimethylethyl)-1;5-(1,1-dimethylethyl)-3-benzenedicarboxylicacid;5-tert-butyl-1,3-benzenedicarboxylicacid;3-TERT-BUTYL-5-CARBOXYLIC ACID BENZOIC ACID;5-TERT-BUTYLISOPHTHAL
Molecular Weight
222.24
Molecular Formula
C12H14O4
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1Synthesis of anionic hypervalent cyclic selenenate esters: relevance to the hypervalent intermediates in nucleophilic substitution reactions at the selenium(II) center.

Selvakumar K1, Singh HB, Goel N, Singh UP, Butcher RJ.

Chemistry. 2012 Jan 27;18(5):1444-57. doi: 10.1002/chem.201003725. Epub 2011 Dec 21.

The synthesis of a diaryl diselenide that contains 2,6-dicarboxylic acid groups, 2,2'-diselanediylbis(5-tert-butylisophthalic acid) (10), is described. Diselenide 10 undergoes intramolecular cyclization in methanol to form a cyclic selenenate ester, 5-tert-butyl-3-oxo-3H-benzo[c][1,2]oxaselenole-7-carboxylic acid (11). The cyclization reaction proceeds more rapidly in the presence of organic bases, such as pyridine, adenine, and 4,4'-bipyridine, to form pyridinium 5-tert-butyl-3-oxo-3H-benzo[c][1,2]oxaselenole-7-carboxylate (14), adeninium 5-tert-butyl-3-oxo-3H-benzo[c][1,2]oxaselenole-7-carboxylate (15), and 4,4'-bipyridiniumbis(5-tert-butyl-3-oxo-3H-benzo[c][1,2]oxaselenole-7-carboxylate) (16), respectively. Read More

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Tel:1-201-478-8534
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