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Home > Product > Material & Chemicals > Biomaterials > 4,4'-Bis(mercaptomethyl)biphenyl

4,4'-Bis(mercaptomethyl)biphenyl | CAS Number: 43012-19-7

Catalog Number
ACM43012197
Product Name
4,4'-Bis(mercaptomethyl)biphenyl
CAS Number
43012-19-7
IUPAC Name
[4-[4-(sulfanylmethyl)phenyl]phenyl]methanethiol
Synonyms
4,4′-Bis(MercaptoMethyl)biphenyl;4,4-Bis(mercaptomethyl)biphenyl 97%
Molecular Weight
246.390960 [g/mol]
Exact Mass
246.05400
Molecular Formula
C14H14S2
Purity
96%
SMILES
C1=CC(=CC=C1CS)C2=CC=C(C=C2)CS
InChIKey
XFHIDPOTWOFDEM-UHFFFAOYSA-N
H-Bond Donor
2
H-Bond Acceptor
2
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1Host-guest interactions in a series of self-assembled As2L2Cl2 macrocycles.

Cangelosi VM1, Zakharov LN, Fontenot SA, Pitt MA, Johnson DW.

Dalton Trans. 2008 Jul 14;(26):3447-53. doi: 10.1039/b802178c. Epub 2008 Apr 18.

The reaction of AsCl3 with H2L (where L = a rigid dithiolate) results in the self-assembly of As2L2Cl2 supramolecular macrocycles. For ligands 4,4'-bis(mercaptomethyl)biphenyl (H2), 4,4'-bis(mercaptomethyl)-trans-stilbene (H2), and 1,4-dimethoxy-2,5-bis(mercaptomethyl)benzene (H2), the macrocyclic cavities of the resulting assemblies are large enough to host aromatic solvent molecules, as revealed by single crystal X-ray structures of the inclusion complexes. Read More

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