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Home > Product > Material & Chemicals > Biomaterials > 3,6-Dioxa-1,8-octanedithiol

3,6-Dioxa-1,8-octanedithiol | CAS Number: 14970-87-7

Catalog Number
ACM14970877
Product Name
3,6-Dioxa-1,8-octanedithiol
Structure
CAS Number
14970-87-7
Synonyms
2,2’-(ethylenedioxy)diethanethiol;2,2’-[1,2-ethanediylbis(oxy)]bis-ethanethio;2,2’-[1,2-ethanediylbis(oxy)]bis-Ethanethiol;Triglycoldimercaptan;ETHYLENE GLYCOL BIS(2-MERCAPTOETHYL) ETHER;1,8-DIMERCAPTO-3,6-DIOXAOCTANE;1,2-BIS(2-MERCAPTOETHOXY)ETHANE;3,6-D
Molecular Weight
182.3
Molecular Formula
C6H14O2S2
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1Green polymer chemistry: investigating the mechanism of radical ring-opening redox polymerization (R3P) of 3,6-dioxa-1,8-octanedithiol (DODT).

Rosenthal-Kim EQ1, Puskas JE2.

Molecules. 2015 Apr 13;20(4):6504-19. doi: 10.3390/molecules20046504.

The mechanism of the new Radical Ring-opening Redox Polymerization (R3P) of 3,6-dioxa-1,8-octanedithiol (DODT) by triethylamine (TEA) and dilute H2O2 was investigated. Scouting studies showed that the formation of high molecular weight polymers required a 1:2 molar ratio of DODT to TEA and of DODT to H2O2. Further investigation into the chemical composition of the organic and aqueous phases by 1H-NMR spectroscopy and mass spectrometry demonstrated that DODT is ionized by two TEA molecules (one for each thiol group) and thus transferred into the aqueous phase. Read More

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