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Home > Product > Material & Chemicals > Polymer/Macromolecule > 3,4-Epoxytetrahydrothiophene-1,1-dioxide

3,4-Epoxytetrahydrothiophene-1,1-dioxide | CAS Number: 4509-11-9

Catalog Number
ACM4509119
Product Name
3,4-Epoxytetrahydrothiophene-1,1-dioxide
Structure
CAS Number
4509-11-9
EC Number
224-827-3
IUPAC Name
6-oxa-3$l^{6}-thiabicyclo[3.1.0]hexane 3,3-dioxide
Synonyms
2,3-epoxytetramethylenesulfone;3,4-epoxysulfolane;tetrahydro-3,4-epoxythiophene1,1-dioxide;thiophene,tetrahydro-3,4-epoxy-,1,1-dioxide;OTAVA-BB BB7018890407;AKOS NCG1-0092;AKOS BBS-00004820;6-OXA-3-THIA-BICYCLO[3.1.0]HEXANE 3,3-DIOXIDE
Molecular Weight
134.15
Exact Mass
134.00400
Molecular Formula
C4H6O3S
Boiling Point
379.2ºC at 760 mmHg
Melting Point
145-150ºC(lit.)
Flash Point
183.1ºC
Density
1.576g/cm3
Purity
96%
SMILES
C1C2C(O2)CS1(=O)=O
InChIKey
SZAIAWVGWTXVMB-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
3
Hazard Statements
Xn
WGK Germany
3
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1Generation of strong, homochiral bases by electrochemical reduction of phenazine derivatives.

Alonso AM1, Horcajada R, Groombridge HJ, Mandalia R, Motevalli M, Utley JH, Wyatt PB.

Chem Commun (Camb). 2004 Feb 21;(4):412-3. Epub 2004 Jan 20.

Electrochemical reduction of enantiomerically pure amino- and alkoxy-phenazine derivatives forms strongly basic radical anions which give asymmetric induction in the conversion of 3,4-epoxytetrahydrothiophene-1,1-dioxide into the allylic ester with facile regeneration of the phenazine.

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA