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Home > Product > Metal Organics > Organic Tin > 2-(Tributylstannyl)thiophene

2-(Tributylstannyl)thiophene | CAS Number: 54663-78-4

Catalog Number
ACM54663784
Product Name
2-(Tributylstannyl)thiophene
Structure
CAS Number
54663-78-4
IUPAC Name
tributyl(thiophen-2-yl)stannane
Synonyms
2-(TRIBUTYLSTANNYL)THIOPHENE;2-THIOPHENYLTRI-N-BUTYLTIN;2-THIENYLTRI-N-BUTYLTIN;TRI-N-BUTYL(2-THIENYL)TIN;TRIBUTYL(2-THIENYL)STANNANE;TRIBUTYL(2-THIENYL)TIN;Thiophenyltrinbutyltin;(2-Thienyl)tributylstannane
Molecular Weight
373.18
Exact Mass
374.10900
Molecular Formula
C16H30SSn
Boiling Point
155ºC0.1 mm Hg(lit.)
Flash Point
221 °F
Density
1.175 g/mL at 25ºC(lit.)
Purity
>98.0%(W)
SMILES
CCCC[Sn](CCCC)(CCCC)C1=CC=CS1
InChIKey
UKTDFYOZPFNQOQ-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
1
Safty Description
S35-S45-S60-S61-S36-S37-S39
Hazard Statements
T,N
WGK Germany
3
Packing Group
III
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1Optical, electrochemical, and magnetic properties of pyrrole- and thiophene-bridged 5,15-diazaporphyrin dimers.

Omomo S1, Maruyama Y, Furukawa K, Furuyama T, Nakano H, Kobayashi N, Matano Y.

Chemistry. 2015 Jan 26;21(5):2003-10. doi: 10.1002/chem.201405482. Epub 2014 Nov 27.

The first examples of pyrrole- and thiophene-bridged 5,15-diazaporphyrin (DAP) dimers are prepared through Stille coupling reactions of nickel(II) and copper(II) complexes of 3-bromo-10,20-dimesityl-5,15-diazaporphyrin (mesityl=2,4,6-trimethylphenyl) with the respective 2,5-bis(tributylstannyl)heteroles. The effects of the heterole spacers and meso nitrogen atoms on the optical, electrochemical, and magnetic properties of the DAP dimers are investigated by UV/Vis absorption spectroscopy, density functional theory calculations, magnetic circular dichroism spectroscopy, cyclic voltammetry, and EPR spectroscopy. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA