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Home > Product > Metal Organics > Organic Tin > 2-(Tributylstannyl)furan

2-(Tributylstannyl)furan | CAS Number: 118486-94-5

Catalog Number
ACM118486945
Product Name
2-(Tributylstannyl)furan
Structure
CAS Number
118486-94-5
Synonyms
2-(TRIBUTYLSTANNYL)FURAN;TRIBUTYL(2-FURYL)TIN;TRI-N-BUTYL(2-FURYL)TIN;Tributyl-(2-furyl)stannane;2-(Tributylstannyl)furane;2-(TRIBUTYLSTANNYL)FURAN 97%;(2-Furyl)tributylstannane;tributyl(furan-2-yl)stannane
Molecular Weight
357.12
Molecular Formula
C16H30OSn
Purity
>97.0%(GC)
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1(E)-5-(Tributylstannylmethylidene)-5H-furan-2-ones: versatile synthons for the stereospecific elaboration of gamma-alkylidenebutenolide skeletons.

Rousset S1, Abarbri M, Thibonnet J, DuchĂȘne A, Parrain JL.

Org Lett. 1999 Sep 9;1(5):701-3.

[reaction: see text] Stereoselective construction of (E)-gamma-tributylstannylmethylidene butenolides 1 was achieved through the palladium-catalyzed tandem cross-coupling/cyclization reactions of tributylstannyl 3-iodopropenoate derivatives with tributyltinacetylene. Iododestannylation of 1 occurs with inversion of the configuration of the exocyclic double bond while the observed selectivity in the Stille reaction was found to be dependent on the nature of the aryl halide.

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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA