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Home > Product > Material & Chemicals > Organic & Printed Electronics > 2 7-Bis(bromomethyl)-9 9-dihexyl-9H-flu&

2 7-Bis(bromomethyl)-9 9-dihexyl-9H-flu& | CAS Number: 187148-75-0

Catalog Number
ACM187148750
Product Name
2 7-Bis(bromomethyl)-9 9-dihexyl-9H-flu&
Structure
CAS Number
187148-75-0
IUPAC Name
2,7-bis(bromomethyl)-9,9-dihexylfluorene
Synonyms
2 7-BIS(BROMOMETHYL)-9 9-DIHEXYL-9H-FLU&
Molecular Weight
520.389
Exact Mass
518.11800
Molecular Formula
C27H36Br2
Melting Point
39-43ºC
Purity
96%
SMILES
CCCCCCC1(C2=C(C=CC(=C2)CBr)C3=C1C=C(C=C3)CBr)CCCCCC
InChIKey
SVNIUQSXMPTBFB-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Safty Description
S26
Hazard Statements
Xi: Irritant;
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1Synthesis of indan-based unusual alpha-amino acid derivatives under phase-transfer catalysis conditions.

Kotha S1, Brahmachary E.

J Org Chem. 2000 Mar 10;65(5):1359-65.

Conformationally constrained cyclic alpha-amino acid derivatives were synthesized under solid-liquid phase-transfer catalysis conditions. This methodology involves the bis-alkylation of ethyl isocyanoacetate with various alpha,alpha'-dibromo-o-xylene derivatives [alpha,alpha'-dibromo-o-xylene 5, 2,3-bis(bromomethyl)-1, 4-dimethoxybenzene 6, 1,2-bis(bromomethyl)-4,5-dibromobenzene 7, 2, 3-bis(bromomethyl)naphthalene 8, 1,8-bis(bromomethyl)-naphthalene 9, 6,7-bis(bromomethyl)-2,2-dimethyl-1H-phenalene-1,3(2H)-dione 10, 2, 3-bis(bromomethyl)-1,4-anthraquinone 11, 6, 7-bis(bromomethyl)quinoxaline 12, 3,4-bis(bromomethyl)furan 13, 1,2, 4,5-tetrakis(bromomethyl)benzene 28, and hexakis(bromomethyl)benzene 30] using potassium carbonate as a base and tetrabutylammonium hydrogensulfate as a phase-transfer catalyst to give corresponding isonitrile derivatives, which upon hydrolysis with HCl in ethanol gave amino esters. Read More

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