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Home > Product > Material & Chemicals > Polymer/Macromolecule > 2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide | CAS Number: 61015-94-9

Catalog Number
ACM61015949
Product Name
2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide
CAS Number
61015-94-9
IUPAC Name
N-tert-butyl-N-$l^{1}-oxidanyl-2-methyl-1-phenylpropan-1-amine
Synonyms
2,2,5-TriMethyl-4-phenyl-3-azahexane-3-nitroxide
Molecular Weight
220.330580 [g/mol]
Exact Mass
220.17000
Molecular Formula
C14H22NO
Purity
96%
SMILES
CC(C)C(C1=CC=CC=C1)N(C(C)(C)C)[O]
InChIKey
VGHCMXLEZFMZOZ-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
1
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1A Proximal Bisnitroxide Initiator: Studies in Low-Temperature Nitroxide-Mediated Polymerizations.

Ruehl J1, Hill NL, Walter ED, Millhauser G, Braslau R.

Macromolecules. 2008 Mar 25;41(6):1972-1982.

Nitroxide-mediated "living" radical polymerization with bisalkoxyamine 2,5,5,8,8,11-hexamethyl-4,9-(1-phenylethoxy)-3,10-diphenyl-4,9-diazadodecane produces polymers of controlled length and narrow molecular weight distributions at temperatures ranging from 70 to 110 °C. Polymerizations were run successfully with styrene (St), tert-butyl acrylate (tBA), and dimethylacrylamide (DMA). EPR measurements of the homolysis of this bisalkoxyamine and monoalkoxyamine 2,2,5-trimethyl-3-(1-phenylethoxy)-4-phenyl-3-azahexane at temperatures ranging from 85 to 105 °C give rate constants for the bisalkoxyamine that are approximately twice as large as those for the monoalkoxyamine. Read More

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