Herzog A1, Jalisatgi SS, Knobler CB, Wedge TJ, Hawthorne MF.
Chemistry. 2005 Dec 9;11(24):7155-74.Rigid camouflaged carborarods constructed from the corresponding C,C'-diethynyl derivatives of B-decamethyl-1,12-dicarbadodecaborane(12) (6) and B-octamethyl-1,7-dicarbadodecaborane(12) (48) have been synthesized by largely conventional organic transformations. These carborarods are the longest discrete rod species available by this method in which B-methylated p-carborane and m-carborane cages are linked through their carbon vertices by using butadiynylene moieties. Read More