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Home > Product > Precious Metal Catalyst > (1,5-Cyclooctadiene)(methoxy)iridium(I)dimer

(1,5-Cyclooctadiene)(methoxy)iridium(I)dimer | CAS Number: 12148-71-9

Catalog Number
ACM12148719
Product Name
(1,5-Cyclooctadiene)(methoxy)iridium(I)dimer
Structure
CAS Number
12148-71-9
MDL Number
MFCD08459360
Synonyms
Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
Molecular Weight
662.86
Molecular Formula
[Ir(OCH3)(C8H12)]2
Melting Point
154-179 °C (D)
Density
g/cm3
Purity
Ir ≥58.0%
Appearance
yellow crystals
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H315-H319-H335
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1Preparation and characterization of novel Os-diolefin dimers: new entry to Os-cyclooctadiene complexes.

Esteruelas MA1, García-Yebra C, Olivan M, Oñate E.

Inorg Chem. 2006 Dec 11;45(25):10162-71.

The complex [H(EtOH)2][{OsCl(eta4-COD)}2(mu-H)(mu-Cl)2] (1) has been prepared in high yield by treatment of OsCl3.3H2O (54% Os) with 1,5-cyclooctadiene in ethanol under reflux. Under air, it is unstable and undergoes oxidation by action of O2 to afford the neutral derivative {OsCl(eta4-COD)}2(mu-H)(mu-Cl)2 (2). The terminal chlorine ligands of the anion of 1 are activated toward nucleophilic substitution. Read More

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