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Home > Product > Material & Chemicals > Polymer/Macromolecule > 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane

1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane | CAS Number: 41203-22-9

Catalog Number
ACM41203229
Product Name
1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane
Structure
CAS Number
41203-22-9
IUPAC Name
1,4,8,11-tetramethyl-1,4,8,11-tetrazacyclotetradecane
Synonyms
1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE;Tetramethylcyclam;1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane,98%;1,5,8,12-Tetramethyl-1,5,8,12-tetraazacyclotetradecane;TetraMethyl-1,4,8,11-tetraazacyclot;N,N,N,N-Tetramethyl-1,4,8,11-tet
Molecular Weight
256.43
Exact Mass
256.26300
Molecular Formula
C14H32N4
Boiling Point
>230 °F
Melting Point
38-42ºC(lit.)
Flash Point
>230 °F
Density
0.876 g/cm3
Purity
96%
Appearance
white to slightly yellow low melting crystalline
SMILES
CN1CCCN(CCN(CCCN(CC1)C)C)C
InChIKey
HRFJEOWVAGSJNW-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
4
Safty Description
S26-S36
Hazard Statements
Xi
WGK Germany
3
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1The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe-O-M Complexes Derived from [FeIV(Oanti/syn)(TMC)]2+ Isomers.

Zhou A, Prakash J, Rohde GT, Klein JE, Kleespies ST, Draksharapu A, Fan R1, Guo Y1, Cramer CJ, Que L Jr.

Inorg Chem. 2016 Dec 21. doi: 10.1021/acs.inorgchem.6b02417. [Epub ahead of print]

Tetramethylcyclam (TMC, 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) exhibits two faces in supporting an oxoiron(IV) moiety, as exemplified by the prototypical [(TMC)FeIV(Oanti)(NCCH3)](OTf)2, where anti indicates that the O atom is located on the face opposite all four methyl groups, and the recently reported syn isomer [(TMC)FeIV(Osyn)(OTf)](OTf). The ability to access two isomers of [(TMC)FeIV(Oanti/syn)] raises the fundamental question of how ligand topology can affect the properties of the metal center. Read More

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